SYNTHESIS OF BEP AND EP-PROPYLTHIOL (FIGURE 1; PATHWAYS B AND C)

The synthesis of this material was extensively described by our research group [38,46]. A certain amount of EP was first brominated with bromine gas under vacuum for 3 h. The resulting material was then dried at 90 °C for 16 h. Magnesium (0.74 g), iron(III) chloride (0.54 g) and dry tetrahydrofu — ran (THF) (30 mL) were mixed under inert atmosphere and stirred for 30 min at 50 °C. Next, 3-chloro-1-propanethiol (0.22 mL) was added and left to stir for 4 h at room temperature. Subsequently, the solution was added to 0.70 g of dry brominated EP. The resulting mixture was stirred for an ad­ditional 24 h at 40 °C. Then, the solid was filtered and washed several times with THF, 2 mol L-1 HCl, H2O and acetone. Finally, the material was dried at 90 °C for 16 h under vacuum (~0.1 Pa) and denoted as EP^CH^-SH.

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